At the moment, I doubt you could. You can email support and find out, though. To my knowledge, they need a lot more delivery drivers for regular orders than Prime Now, and they were previously trying to switch Prime Now drivers over to .com because there were too many. I believe you would have a harder time getting hours as well. From what I've read here, it seems like blocks for .com are a little easier to grab.... I believe they said that in the future, drivers will be able to do both, but for now it's one or the other.I currently do dot-com deliveries. How would I get Prime Now deliveries?